二軸延伸ポリ(ρ−フェニレンスルフィド)フィルムの延伸に伴う各結晶面法線の配向分布関数の塑性滑りによるシミュレーション第2報 ポリ(ρ−フェニレンスルフィド)フィルムの二軸延伸に伴う各結晶面法線の配向分布関数のシミュレーションと実験データとの比較
Simulation of Orientation Distribution Function for Biaxial Stretching of Poly (ρ-Phenylene Sulfide) Film Calculated with the Plastic Slip ModelPart II : Orientation Distribution Function of Each Crystal Plane in Biaxial Stretching of Poly (ρ-Phenylene Sulfide) Film
波多野靖・水上 潤・南条 誠・日比貞雄・谷 智・川上恒夫
Hatano, Yasushi / Mizukami, Jun / Nanjo, Makoto / Hibi, Sadao / Tani, Satoru / Kawakami, Tsuneo
We have evaluated the orientation distribution function for each crystal plane under biaxial stretching in poly (ρ-phenylene sulfide) films. The pole figure device familiar in X-ray diffraction was used. These distribution functions were compared with a simulation of orientation in crystallites after biaxial stretching by assuming polycrystalline aggregations. We analyzed the mechanism of orientation for the strip biaxial stretching process in which the (100), <001> and {110}, <001> slip systems dominated in four types of slip system by applying the maximum plastic work principle.
Key words: Crystallites / Poly (ρ-phenylene sulfide) / Orientation distribution function / Slip system / Maximum plastic work